Sensitization of low bandgap polymer bulk heterojunction solar cells

Spectroscopic analysis of NIR-dye sensitization in bulk heterojunction polymer solar cells.

The photovoltaic conversion efficiency for near-infrared (NIR) sunlight is improved successfully by dye sensitization of bulk heterojunction polymer solar cells, in which the active layer was prepared by a ternary blend of poly(3-hexylthiophene), a fullerene derivative (1-(3-methoxycarbonyl)propyl-1-phenyl-[6,6]-methanofullerene), and an NIR dye, silicon phthalocyanine bis(trihexylsilyl oxide)....

Modeling and simulation of bulk heterojunction polymer solar cells

This review summarizes the optical and electrical models of bulk heterojunction (BHJ) polymer solar cells (PSCs) and numerically simulates and analyzes the performance of the PSCs. A complete simulation of a conventional BHJ device based on the polymer P3HT is presented and results are compared with the experimental data. Key factors affecting the device performance, including the photo absorpt...

Morphology of polymer/fullerene bulk heterojunction solar cells

Within the different organic photovoltaic devices the conjugated polymer/fullerene bulk heterojunction approach is one of the foci of today’s research interest. These devices are highly dependent on the solid state nanoscale morphology of the two components (donor/acceptor) in the photoactive layer. The need for finely phase separated polymer–fullerene blends is expressed by the limited exciton...

Streamlined microwave-assisted preparation of narrow-bandgap conjugated polymers for high-performance bulk heterojunction solar cells.

The most efficient plastic solar cells comprise a blend of conjugated polymer and a suitable electron acceptor, typically a fullerene derivative. Therefore narrow-bandgap conjugated polymers are currently sought for the fabrication of such devices. A significant challenge is being able to predict device function and performance from consideration of the molecular connectivity and dimensions of ...

Bulk Heterojunction Solar Cells — Opportunities and Challenges